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Arsenic In Drinking Water: What You Need To Know

Christina Liu @ Tuesday, August 15, 2017 at 11:10 pm -0400

We do everything from providing in-depth breakdowns of common contaminants to reports on city tap water quality. We’re keeping it going by writing about another common heavy metal that can contaminate drinking water: Arsenic.

How Are We Exposed To Arsenic?

Humans are exposed to inorganic arsenic mainly through contaminated drinking water. Some water sources in the United States have higher naturally occurring levels of inorganic arsenic than other regions. Levels of inorganic arsenic in soil typically range from 1-40mg/kg and the EPA recommended concentration in water supplies is less than 10µg/L. However, higher levels can occur near natural mineral deposits, mining sites, smelting industries, and regions where pesticides have been applied.

In addition, workers who use arsenic compounds for smelting, pesticide manufacturing and application, and wood preservation are at a higher risk for arsenic poisoning.

Below is a map published by the United States Geological Survey (USGS) which shows the concentration of arsenic in groundwater in the United States. It’s estimated that 2 million Americans have private wells and drink water with unsafe levels of Arsenic. If you live in one of the areas with high arsenic concentration, and get your drinking water from a private well, we highly recommend getting your water tested by a qualified laboratory

arsenic in well water

Source: https://www.usgs.gov/mission-areas/water-resources/science/arsenic-and-drinking-water?qt-science_center_objects=0#qt-science_center_objects.

Arsenic Toxicity

Arsenic is a toxic heavy metal several epidemiological studies have reported a strong association between arsenic exposure, cancer, and systemic diseases. In fact, arsenic exposure affects virtually all organ systems including the cardiovascular, dermatologic, nervous, hepatic, renal, gastrointestinal, and respiratory systems. The severity of the adverse health effects is related to both the chemical form of arsenic and the dosage. Evidence of carcinogenicity due to arsenic exposure is very strong, but the specific mechanism by which it causes cancer is not completely understood.

Recent studies have found that pregnant women are especially susceptible to the harmful effects of arsenic exposure. Arsenic exposure can drastically impact reproductive outcomes, affect fetal development, and can lead to long term health problems. However, the association between chronic arsenic exposure and adverse pregnancy outcomes is not widely recognized.

What Can I Do To Reduce My Exposure To Arsenic?

A growing number of people are realizing that regulatory limits are not always in line with current toxicological studies, and are taking steps to minimize exposure to heavy metals like arsenic, lead, mercury, and chromium 6 from their drinking water, even if their city is "in compliance" with EPA regulations.

Unlike lead, which leaches into water from pipes, arsenic comes from the source water itself, so flushing pipes or replacing plumbing will not reduce arsenic concentrations. Boiling water also does NOT remove arsenic. Arsenic must be removed using a water filter that is specifically designed to do so.

Whole House Filters

While some whole house filters can reduce arsenic levels to some extent, we don't recommend most whole house water filters due to their high cost and unnecessary filtration of water when it isn't consumed (such as flushing the toilet). Instead, we advocate for point-of-use water filters, which are more efficient and cost-effective for filtering water that is being consumed. 

In cases where arsenic levels are very high and exceed our performance specifications, we may suggest considering a specialized arsenic removal filter at your home's point of entry to bring the levels within our operating parameters. Once this is achieved, you can use a Hydroviv filter at your point of use for further arsenic reduction.

Point Of Use Water Filters For Arsenic

The most cost-effective method of arsenic, chromium 6, and contaminants filtration is through a point of use water filter. When shopping for these systems, we encourage you to make sure that the filter actually filters arsenic (most don't). While we believe that our advanced under sink filters have unique benefits and use filtration media that effectively remove both types of inorganic arsenic, some systems that use reverse osmosis can be a good choice for people who are willing to accept the downsides. No matter what... make sure that your filter removes what you think it does!

As always, feel free to take advantage of our “help no matter what” approach to technical support! While we do make water filters that remove arsenic, our water nerds are happy to answer your questions about the effects of arsenic in water, even if you have no intention of purchasing a Hydroviv Water Filter. Reach out by dropping us an email (hello@hydroviv.com) or through the live chat on our webpage.

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EPA Superfund Sites: An Overview on Hazards and the Process

Analies Dyjak @ Monday, August 7, 2017 at 6:00 pm -0400

Emma Schultz, M.S.  |  Scientific Contributor
Updated 12/1/2023 to include latest numbers of Superfund sites by state. 

Do you know where your nearest EPA Superfund Site is? Chances are there is one close by, given that one out of every five Americans lives within three miles of an EPA-designated major hazardous waste site. There are two sites located within four miles of my childhood home, in an idyllic and quiet suburb of St. Paul, Minnesota. I now live within the same distance of five sites -- and I had no clue. 

Superfund Sites - Environmental Hazards

What does it mean to be living so close to so much waste? Common contaminants found at EPA Superfund Sites include asbestos, lead, radiation, and dioxins; these all pose significant risks to human and environmental health. In addition, hazardous substances can leach into the soil from ground level or contaminated water, and can then migrate into nearby homes through subsurface intrusion, entering buildings through foundation cracks and sewer lines. This vapor intrusion then poses further risk to nearby residents, inside of their homes where they would otherwise be inclined to feel safe. Obviously, proximity to a Superfund site is critical; four miles' distance poses a decreased health risk as compared to a mere forty feet.

What Is The Superfund Process?

The concept of EPA Superfund Sites is widely known and understood, but the intricacies of the program and the approach to hazardous waste mitigation are elaborate and prolonged, as can be expected of any federally-funded long-term project.

History: 

In December of 1980, President Jimmy Carter signed into law the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), now known better as Superfund, which authorized the EPA to remediate hazardous waste spills and sites, and obliged those responsible for the waste - the Potential Responsible Party - to either clean it up on their own dollar or offset the cost of EPA-led cleanup efforts. Superfund had abundant funding early in its existence due to taxes levied on chemicals and oil; those taxes, however, lapsed in 1995, and financing now comes from taxpayers.

Process and Stages:

There are multiple stages in the Superfund process once a site is identified, with the first step being a Preliminary Assessment or Site Inspection. If the site is an emergency such as a chemical spill, Removal Action is taken. Otherwise, Remedial Action is planned for, which often leads to years-long planning, cleanup, and remediation. Community involvement is frequently key during the early stages of Superfund designation, and the Technical Assistance Services for Communities (TASC) program is an outreach effort designed to connect with citizens and businesses for the duration of a Superfund's existence.

After initial study, EPA Superfund Sites are given a score on the Hazard Ranking System. If a site poses enough of a threat to environmental and human health, the EPA announces its addition to the National Priorities List (NPL), pending public comment and input. NPL sites are eligible for extensive, and often long-term, federal funding through the Superfund program. These NPL-listed sites are now officially Superfund sites.

Following NPL designation, a Remedial Investigation and Feasibility Study is conducted. The Remedial Investigation collects information on-site such as water and soil samples, and the follow-up Feasibility Study analyzes various cleanup methods. The EPA then selects the most suitable cleanup alternative and provides it to the community as a Proposed Plan.

A Record of Decision notes the cleanup alternative chosen for the site. In the Remedial Design phase, the cleanup plans are drawn up, and are finally acted upon in the Remedial Action stage. A goal of Remedial Action is to return sites to productive use as quickly as possible. Whether 'productive' means industrial, housing, commercial, or greenspace depends on conversations and input from the surrounding community.

A review of EPA Superfund Site cleanup efforts occurs every five years. If cleanup goals have all been met, a portion or whole of a Superfund site may then be listed for removal from the NPL. In theory, meeting all cleanup goals sounds achievable - especially given the lengthy planning and implementation phases - but there are many sites that remain listed decades later, because groundwater and soil are still polluted.

Where Can You Learn More About Superfund Sites?

Finding out if there are Superfund sites near your home is the first step that all concerned citizens should take. There are 10 Regional Superfund Community Involvement Offices around the country that exist to take your questions and concerns regarding existing or potential Superfund sites. 

Here is the latest list of states and the number of Superfund sites they contain. Be aware that not all toxic contaminants are on the list for contaminated sites to qualify for Superfund. For example, PFAS contaminated sites are not yet regulated under CERCLA. 
States With Superfund Sites

Resources for homeowners:

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Polychlorinated Biphenyls (PCBs): Everything You Need To Know

Analies Dyjak @ Saturday, August 5, 2017 at 3:56 pm -0400

Stephanie Angione, Ph.D.  |  Scientific Contributor

What Are Polychlorinated Biphenyls (PCBs)?

Polychlorinated Biphenyls (PCBs) are a class of industrial chemical that were widely manufactured in the US from the 1930s through the 1970s for use in electric equipment such as capacitors and transformers, and also as heat transfer fluids, plasticizers, adhesives, fire retardants, inks, lubricants, cutting oils, pesticide extenders, and in carbonless copy paper.
 
While PCB production slowed in the 1960s and was banned completely in the US in 1979, they are still found in industrial applications due to their chemical longevity. The US congressional ban was enacted due to the fact that PCBs are persistent organic pollutants, which create long lasting environmental toxicity and cause harmful health effects. Products that contain PCBs include old fluorescent lighting fixtures, PCB capacitors in old electrical appliances (pre-1978) and certain hydraulic fluids.
 
Nearly 2 million tons of PCBs have been produced since 1929, 10% of which persists in the environment today. Generally, environmental concentrations of PCBs are low, but due to their chemical inertness they are largely resistant to chemical breakdown or thermal destruction, and thus accumulate in the environment. Additionally, PCBs are highly fat soluble, resulting in the build up of PCBs in animal fat, resulting in higher concentrations of PCBs in top food chain consumers (e.g. predatory fish, large mammals, humans).
 

Where Are PCBs Found In The Environment?

Polychlorinated Biphenyls accumulate primarily in water sources, organic portions of surface soil, and in living organisms.
 

Water

Surface water that is contaminated with PCB waste generally has high levels of PCBs in sediment, as the PCBs attach to organic matter. PCBs can be slowly released from the sediment into the water and evaporate into the air, especially at higher temperatures.

Air

PCBs have been detected throughout the atmosphere, and can be transported globally through air. Concentrations of PCBs in the air are generally the lowest in rural areas and highest in large cites. Areas that are close to bodies of water that were highly contaminated with PCBs from industrial waste (e.g. Lake Michigan, Hudson River) can have higher air concentrations, due to evaporation of PCBs into the air over time.  


Living Organisms

PCBs accumulate in living organisms via bioaccumulation, or uptake from the environment, as well as biomagnification, from consumption along the food chain. Bioaccumulation is typically highest in aquatic species, with bottom feeding species having the highest levels of PCBs due to accumulation in sediment.  PCBs biomagnify up the food chain, as bottom feeders like shellfish are eaten by other species, and thus the greatest levels are found in large predatory fish. This process can also occur on land, as PCB contamination in soil is transferred up the food chain to insects, birds and mammals. Thus, one of the largest sources of PCB exposure and accumulation in humans is from food, specifically meat and fish.

How Do PCBs Impact Humans?

While PCBs have been classified as probable human carcinogens, there is no evidence that the low levels of PCBs in the environment cause cancer. Exposure to high levels of PCBs have primarily occurred through workplace exposure in people who work in plants that manufacture the chemicals. Studies of workers exposed to high PCB levels have shown association with certain types of cancer. These high levels of exposure have also been known to cause liver damage, skin lesions called chloracne, and respiratory problems.

Exposure to PCBs during pregnancy can result in developmental and behavioral deficits in newborns. Additionally, there is evidence that reproductive function can be disrupted due to PCB exposure. Women of childbearing age, or those who are pregnant or nursing should be aware of fish and shellfish advisories to limit consumption of PCB contaminated fish.
There are additional studies that suggest PCB exposure can cause health effects including thyroid dysfunction, liver dysfunction, as well as adverse cardiovascular, gastrointestinal, immune, musculoskeletal, and neurological effects.

How Are PCBs Regulated & Monitored In The US?

With so many sources of PCB exposure from food and water sources, the US government has guidelines on the amount of allowable environmental PCB contamination for each.  

Food

The FDA enforces a tolerance level in fish of 2 ppm, and overall 0.2 -3.0 ppm for all foods. PCBs in paper food packaging are limited to 10 ppm.
 
If fishing recreationally and you plan to eat your catch, check if any local fish consumption guidelines exist for your area. The EPA maintains a national database of fish and shellfish advisories issued by each state. These consumption advisories may recommend limiting the amount of a certain fish consumed, or from specific waters or water sources. As of 2011, five areas have advisories for PCBs in freshwater sources (Missouri, Minnesota, Maryland, Indiana, and District of Columbia) and nine states (Connecticut, Delaware, Maine, Maryland, Massachusetts, New Hampshire, New Jersey, New York, and Rhode Island) have PCB advisories for coastal waters.

Drinking Water

Under the Clean Water Act, industrial discharge of Polychlorinated Biphenyls in water is prohibited. The goal is to reach zero contamination in drinking water, but the enforceable maximum level is 0.0005 part per million (ppm).  Additionally, industries are required to report spills or accidental releases to the EPA. 

Routine monitoring of PCB levels in drinking water require the water supplier to maintain the limit enforced by the EPA and must make the data regarding water quality and contaminants public. Every year, the EPA requires water suppliers nationwide to provide a Consumer Confidence Report (CCR), which will include information about water treatment and any known contaminants. These reports are available on the EPA website and should be available on your water company’s website. Additionally, the supplier is required to alert customers of increased levels of PCB contamination as soon as possible.
 
If you get water from a household well, the local health department should have information about ground water quality and contaminants of concern, but it is often a good idea to have your water tested by a certified laboratory if you are worried about PCB (or other) contaminants. The EPA’s Safe Drinking Water Hotline (800-426-4791) can provide additional resources in your local area.

How Can I Remove PCBs From My Water?

If your water has high levels of PCBs in it,  the water should also not be used to drink, prepare or cook food,  or given to pets for consumption without first treating it.  Fortunately, PCBs are effectively removed from water by filters that use activated carbon as part of their active filtration media blend.
 
Hydroviv makes it our business to help you better understand your water.  As always, feel free to take advantage of our “help no matter what” approach to technical support!  Our water nerds will work to answer your questions, even if you have no intention of purchasing one of our water filters.  Reach out by dropping us an email (hello@hydroviv.com) or through our live chat. You can also find us on Twitter or Facebook!

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Digging Into The Environmental Working Group Tap Water Database

Analies Dyjak @ Saturday, July 29, 2017 at 6:16 pm -0400

Eric Roy, Ph.D.  |  Scientific Founder

This past week, the Environmental Working Group (EWG) released a website where people punch in their zip code, and view contaminants found in their water. As a company that uses water quality data to optimize each customer’s water filter, we applaud EWG for putting in the enormous amount of time & effort to build the database so the public can learn about their water. Unfortunately, we are seeing that these data are being used to generate inflammatory headlines, which can leave consumers confused and unnecessarily panicked.

We will be updating this water quality database blog post as more questions come in. If you have your own question, please reach out to us (hello@hydroviv.com). One of our water nerds will do their best to get back to you very quickly, even if it’s outside of our business hours.

Frequently Asked Questions 

Updated July 31, 2017

Are All Potential Contaminants Listed In The EWG Tap Water Database?

No. The EWG Tap Water Database pulls data from municipal measurements, but municipalities are only required to test for certain things. Simply put, you can’t detect what you don’t look for. One example of this can be seen by punching in Zip Code 28402 (Wilmington, North Carolina) into the EWG Tap Water Database. GenX, a chemical that has been discharged into the Cape Fear River by Chemours since PFOA since 2010, is not listed, even though it’s been in the center of a huge topic of conversation for the past 2 months in the local media.

Why Is The “Health Guideline” Different Than The “Legal Limit?”

The two different thresholds use different criteria. For example, the “Health Guideline” cited by EWG for carcinogens is defined by the California Office of Environmental Health Hazard Assessment (OEHHA) as a one-in-a-million lifetime risk of cancer, while the “Legal Limit” refers to the MCL which is the limit that triggers a violation by EPA. The OEHHA's criteria are established by toxicological techniques, while the EPA limits are negotiated through political channels. We wrote an article that addresses this topic in much more detail for those who are interested.

Why Am I Just Learning About This Now?

The EPA's Safe Drinking Water Act requires municipalities to make water quality test data public in Consumer Confidence Reports. These reports are required to talk about the water's source, information about any regulated contaminants found in the water, health effects of any regulated contaminant found above the regulated limit, and a few other things. As discussed before, the data in the EWG report use different criteria than the EPA, and it's hard for people to make sense of what's what.

Are The Data Correct If My Water Comes From A Private Well?

No. The EWG Tap Water Database only has data for municipal tap water. Private wells are completely unregulated, and there's no requirement to conduct testing. If you'd like us to dig into our additional water quality databases to help you understand likely contaminants in your private well, we're happy to do so. We don't offer testing services, but we're happy to help you find an accredited lab in your area, give advice on which tests to run, and help you interpret the results! We offer this service for free.

What About My City's Water Quality?

Hydroviv makes it our business to help you better understand your water. As always, feel free to take advantage of our “help no matter what” approach to technical support! Our water nerds will work to answer your questions, even if you have no intention of purchasing one of our water filters. Reach out by dropping us an email (hello@hydroviv.com) or through our live chat. You can also find us on Twitter or Facebook!

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Chromium 6 In Drinking Water: What You Need To Know

Analies Dyjak @ Monday, July 17, 2017 at 6:02 pm -0400

Wendy Spicer, M.S.  |  Scientific Contributor
***Updated 10/27/2022 to include recent health studies and regulatory status. 

If you have seen the movie Erin Brockovich, you are familiar with chromium 6 (also known as hexavalent chromium and chromium VI). The film tells the story of a legal clerk turned activist who uncovers that a California utility company, Pacific Gas and Electric (PG&E), was knowingly dumping chromium 6 waste and contaminating the local water supply. Brockovich’s law firm, Masry and Vititoe, represented over 600 clients in a lawsuit against PG&E which settled for $333 million dollars in 1993. Despite the success and fame of this story, chromium 6 water contamination remains largely unregulated and problematic across the United States. The Environmental Working Group estimated that in 2015, water supplies serving over 218 million Americans were contaminated with chromium 6.

What Is Chromium?

It is important to note that there are 2 very different forms of chromium that are often grouped together when reporting contaminant levels. These two different types vary based on their oxidation states, meaning that they differ in the number of electrons surrounding the atom’s nucleus. Chromium (III), or trivalent chromium is a naturally occurring element that is an essential nutrient, and is beneficial, not toxic to humans. In fact, chromium(III) plays a role in glucose, fat, and protein metabolism by increasing the effect of insulin.

However, chromium 6 is the highly-toxic form of chromium. Industrial discharge is the largest source of chromium 6 in our environment and is released into air and wastewater by metal processing facilities, tannery facilities, chromate production, stainless steel welding, ferrochrome production, and pigment production. The major way that most people are exposed to chromium 6 is through contaminated food and water.

What Are The Adverse Health Effects Of Chromium in Water?

There is strong evidence that chromium 6 is a human carcinogen. The most recent EPA draft toxicity review states "Cr(VI) is likely to be carcinogenic to humans by the oral route of exposure.” 

Specifically, this study suggests that chromium 6 causes stomach cancer in humans, consistent with previous tumor results reported in rodent studies. Chromium 6 exposure is also known to cause multiorgan toxicity such as kidney damage, allergy, and asthma. This study compared the toxicity of chromium 3 to chromium 6 in kidney cells, and scientists observed toxic effects in cells treated with chromium 6 but not with chromium 3.

In addition to being a likely carcinogen, the most recent EPA draft toxicity review discusses negative health effects affecting organ systems  including gastrointestinal, liver, immune, hematologic, as well as the male reproductive system. In addition, the developing fetus is considered especially susceptible because Chromium 6 was determined as a likely cause of developmental toxicity in humans

Chromium 6 is also a known endocrine-disrupting chemical, and this study documented that environmental exposure to chromium 6 caused detrimental reproductive effects in women and negative health effects in infants in California. In fact, the scientists reported that women with occupational chromium 6 exposure experienced infertility, pregnancy loss, spontaneous abortion, and stillbirth.

Breathing high levels of chromium 6 can cause irritation to the lining of the nose, and nose ulcers. Lung and respiratory cancers are more common in industrial workers (where it is more likely to be inhaled) while gastrointestinal tumors are more common in humans and animals exposed to chromium 6 in drinking water. Accidental or intentional ingestion of extremely high doses of chromium 6 compounds can cause acute respiratory, cardiovascular, gastrointestinal, hematological, hepatic, renal, and neurological distress which may result in death.

Is Chromium 6 Regulated?

Chromium 6 in drinking water is not currently regulated by any State or at the Federal Level. However, the California Water Resources Control Board’s Drinking Water Program is the first in the nation to unveil a proposal to set a “maximum contaminant level” (MCL) of 10 parts per billion, or ppb, in water. The board is also proposing to set the “detection limit,” which would trigger reporting, at 0.05 ppb. The current Public Health Goal in California (the level below which there is no expected health issues) for Chromium-6 is 0.02 ppb.

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